Masterless Starglitter, Genshin Impact Wiki

Masterless Starglitter is a special currency that is used to purchase rarer items, Intertwined or Acquaint Fates, or a monthly rotation of characters and weapons from Paimon's Bargains. If a player obtains a 4/5★ weapon from a Wish or a character that they already own, they will receive Masterless Starglitter. The amount rewarded differs on the quality of the item or character as well as how many times a player has pulled duplicates of that same character before. Players cannot acquire Starglitt

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It seems the background is different when you buy a character with Starglitter vs. pulling them on a banner : r/Genshin_Impact

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